Room-temperature nickel-catalysed cross-couplings of aryl chlorides with arylzincs

Chem Commun (Camb). 2011 Feb 7;47(5):1598-600. doi: 10.1039/c0cc03064c. Epub 2010 Nov 26.

Abstract

P,N,O-chelate nickel complexes efficiently catalyse the cross-coupling reaction of aryl chlorides with arylzinc reagents in a 1:1 THF-NMP mixture. The reactions proceed at room temperature with low catalyst loading.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Hydrocarbons, Chlorinated / chemistry*
  • Molecular Structure
  • Nickel / pharmacology*
  • Organometallic Compounds / chemistry*
  • Solvents / chemistry
  • Zinc / chemistry*

Substances

  • Hydrocarbons, Chlorinated
  • Organometallic Compounds
  • Solvents
  • Nickel
  • Zinc