High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework

Chem Commun (Camb). 2011 Jan 7;47(1):538-40. doi: 10.1039/c0cc02490b. Epub 2010 Nov 19.

Abstract

A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and shows guest dependent magnetic modulation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Hot Temperature*
  • Hydrogen / chemistry*
  • Magnetics*
  • Models, Molecular
  • Organometallic Compounds / chemistry*
  • Porosity
  • Surface Properties

Substances

  • Organometallic Compounds
  • Hydrogen