Abstract
Cycloaddition of 3-carbomethoxy-2H-pyran-2-one to a vinylated sugar followed by the loss of bridging CO(2) from the cycloadduct affords a cyclohexadiene which can be manipulated to a carbasugar-sugar pseudodisaccharide.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carbasugars / chemistry*
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Cyclization
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Disaccharides / chemical synthesis*
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Hydrogen / chemistry*
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Molecular Structure
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Pyrans / chemistry*
Substances
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Carbasugars
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Disaccharides
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Pyrans
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Hydrogen