A dimeric aluminium hydroxide supported by a new disiloxide ligand

Katja Weichert; Bryan Carlson; Helmut Reinke; Clemens Krempner

doi:10.1039/c0dt00507j

A dimeric aluminium hydroxide supported by a new disiloxide ligand

Dalton Trans. 2010 Dec 28;39(48):11513-5. doi: 10.1039/c0dt00507j. Epub 2010 Nov 4.

Authors

Katja Weichert¹, Bryan Carlson, Helmut Reinke, Clemens Krempner

Affiliation

¹ Institut für Chemie der Universität Rostock, A.-Einstein-Str., 3a, 18059, Rostock, Germany.

PMID: 21052591
DOI: 10.1039/c0dt00507j

Abstract

The synthesis and structure of a dimeric aluminium hydroxide complex containing the novel chelating 1,4-disiloxide ligand [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)(2-) (2)-2H is reported. [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlOH (4) was prepared by careful hydrolysis of [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlMe·THF (3).