A simple recipe for an efficient TiO2 nanofiber-based dye-sensitized solar cell

A Sreekumaran Nair; Rajan Jose; Yang Shengyuan; Seeram Ramakrishna

doi:10.1016/j.jcis.2010.09.042

A simple recipe for an efficient TiO2 nanofiber-based dye-sensitized solar cell

J Colloid Interface Sci. 2011 Jan 1;353(1):39-45. doi: 10.1016/j.jcis.2010.09.042. Epub 2010 Sep 22.

Authors

A Sreekumaran Nair¹, Rajan Jose, Yang Shengyuan, Seeram Ramakrishna

Affiliation

¹ Healthcare and Energy Materials Laboratory, Nanoscience and Nanotechnology Initiative, National University of Singapore, 117576 Singapore, Singapore. nniansn@nus.edu.sg

PMID: 20934187
DOI: 10.1016/j.jcis.2010.09.042

Abstract

Development of highly efficient dye-sensitized solar cells (DSSCs) with good photovoltaic parameters is an active research area of current global interest. In this article, we provide a simple recipe for the fabrication of electrospun TiO(2) nanorod-based efficient dye-sensitized solar cell using a Pechini-type sol. The Pechini-type sol of TiO(2) nanofibers produces a highly porous and compact layer of TiO(2) upon doctor-blading and sintering without the need for an adhesion and scattering layers or TiCl(4) treatment. The best nanofiber DSSCs with an area of ~0.28 cm(2) shows an efficiency of ~4.2% under standard test conditions (100 mW/cm(2), 25°C and AM1.5 G) and an incident photon-to-electron conversion efficiency (IPCE) of ~50%. Impedance measurements show lower charge transfer resistance that improved the fill factor. We believe that simple approaches such as the present one to develop nanofiber DSSCs would open up enormous possibilities in effective harvesting of solar energy for commercial applications, considering the fact that electrospinning is a cost-effective method for the mass scale production of nanofibers and nanorods.