Self-assembled molecular wires from organoiron metalloligands and ruthenium tetramesitylporphyrin

Floriane Malvolti; Paul Le Maux; Loic Toupet; Mark E Smith; Wing Y Man; Paul J Low; Erwan Galardon; Gérard Simonneaux; Frédéric Paul

doi:10.1021/ic1012445

Self-assembled molecular wires from organoiron metalloligands and ruthenium tetramesitylporphyrin

Inorg Chem. 2010 Oct 18;49(20):9101-3. doi: 10.1021/ic1012445.

Authors

Floriane Malvolti¹, Paul Le Maux, Loic Toupet, Mark E Smith, Wing Y Man, Paul J Low, Erwan Galardon, Gérard Simonneaux, Frédéric Paul

Affiliation

¹ Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, Campus de Beaulieu, Bât. 10C, 35042 Rennes Cedex, France.

PMID: 20863091
DOI: 10.1021/ic1012445

Abstract

A trinuclear assembly of two (η(2)-dppe)(η(5)-C(5)Me(5))FeC≡C(4-Py) (Py = pyridyl) metalloligands apically coordinated to a ruthenium(II) tetramesitylporphyrin is demonstrated to behave as a molecular wire in the monooxidized state.