Abstract
The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aziridines / chemistry
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Copper / chemistry*
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Crystallography, X-Ray
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Models, Molecular
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Molecular Conformation
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry*
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Stereoisomerism
Substances
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Aziridines
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Organometallic Compounds
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phosphazine
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Copper