The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly

Rosa Pedrido; Miguel Vázquez López; Lorenzo Sorace; Ana M González-Noya; Magdalena Cwiklinska; Vanesa Suárez-Gómez; Guillermo Zaragoza; Manuel R Bermejo

doi:10.1039/c0cc00338g

The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly

Chem Commun (Camb). 2010 Jul 14;46(26):4797-9. doi: 10.1039/c0cc00338g. Epub 2010 May 27.

Authors

Rosa Pedrido¹, Miguel Vázquez López, Lorenzo Sorace, Ana M González-Noya, Magdalena Cwiklinska, Vanesa Suárez-Gómez, Guillermo Zaragoza, Manuel R Bermejo

Affiliation

¹ Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain. rosa.pedrido@usc.es

PMID: 20508881
DOI: 10.1039/c0cc00338g

Abstract

A method to modulate the strength of the superexchange coupling interaction in dinuclear helical assemblies based on the coordination preferences of the metal centres is described.