1 MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
An unprecedented organic-inorganic hybrid material with 3D inorganic and 3D organic connectivity has been constructed based on Cd(II) and tetrazolate-5-carboxylate, which shows a highly connected trinodal (4,8,16-c) topological net and SHG activity.