Abstract
New Ir-NHC complexes based on different heterocyclic moieties like imidazole, benzimidazole and imidazolidine are presented and tested in transfer hydrogenation catalysis. A broad range of steric and electronic properties of NHC ligands is covered to give an idea for catalyst design from the experimental point of view.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Crystallography, X-Ray
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Heterocyclic Compounds / chemistry*
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Hydrogenation
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Iridium / chemistry*
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Ligands
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Methane / analogs & derivatives*
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Methane / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Stereoisomerism
Substances
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Heterocyclic Compounds
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Ligands
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Organometallic Compounds
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carbene
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Iridium
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Methane