AgOC(CF(3))(3): an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes

Dalton Trans. 2009 Sep 21:(35):6956-9. doi: 10.1039/b900136k. Epub 2009 Jun 8.

Abstract

AgOC(CF(3))(3), a soluble source, was found to be a convenient reagent for the one-pot preparation of Ag-NHC and M-NHC complexes starting from imidazoliums (M = Au, Ir, Pd and Ru).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Heterocyclic Compounds / chemistry*
  • Methane / analogs & derivatives*
  • Methane / chemistry
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Stereoisomerism
  • Transition Elements / chemistry*

Substances

  • Heterocyclic Compounds
  • Organometallic Compounds
  • Transition Elements
  • carbene
  • Methane