High-speed off-axis Cavity Ring-Down Spectroscopy with a re-entrant configuration for spectral resolution enhancement

Opt Express. 2010 Mar 1;18(5):4845-58. doi: 10.1364/OE.18.004845.

Abstract

Monitoring of changing samples by Cavity Ring-Down Spectroscopy (CRDS) is possible using fast frequency scans of the laser and/or the cavity resonance. Mode-matched cavity excitation improves performance of fast CRDS but data-points result separated by the cavity Free Spectral Range (FSR): low pressure samples demand long cavities. We demonstrate fast CRDS with off-axis injection of a "re-entrant" resonator yielding FSR/N data-points separation. Our N = 4 short-cavity setup is found to perform well compared with other fast-CRDS implementations. Interestingly, the intrinsic chirped ringing affecting ring-down signals in mode-matched fast-CRDS disappear with off-axis injection. This is due to a fine splitting of the re-entrant-cavity degenerate groups of modes by astigmatism.

Publication types

  • Research Support, Non-U.S. Gov't