Pd(II)/HPMoV-catalyzed direct oxidative coupling reaction of benzenes with olefins

Yasushi Obora; Yasutaka Ishii

doi:10.3390/molecules15031487

Pd(II)/HPMoV-catalyzed direct oxidative coupling reaction of benzenes with olefins

Molecules. 2010 Mar 9;15(3):1487-500. doi: 10.3390/molecules15031487.

Authors

Yasushi Obora¹, Yasutaka Ishii

Affiliation

¹ Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan. obora@kansai-u.ac.jp

Abstract

The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)2/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.

Publication types

Research Support, Non-U.S. Gov't
Review

MeSH terms

Alkenes / chemistry*
Benzene / chemistry*
Molybdenum / chemistry*
Oxidation-Reduction
Palladium / chemistry*
Phosphoric Acids / chemistry*
Vanadates / chemistry*

Substances

Alkenes
Phosphoric Acids
Vanadates
Palladium
Molybdenum
Benzene