Superhydrophobic PLA fabrics prepared by UV photo-grafting of hydrophobic silica particles possessing vinyl groups

J Colloid Interface Sci. 2010 Apr 15;344(2):584-7. doi: 10.1016/j.jcis.2010.01.024. Epub 2010 Jan 18.

Abstract

Superhydrophobic poly(lactic acid) (PLA) fabrics are prepared by UV photo-grafting of hydrophobic silica particles possessing vinyl functional groups on the surfaces, which is a novel one-step process to provide surface with roughness as well as hydrophobicity simultaneously. For this purpose, hydrophobic silica particles with vinyl groups and average diameter of 1.51+/-0.05 microm are synthesized via a sol-gel process. The silica particles possessing vinyl groups are found to be effectively immobilized on PLA fabrics via UV photo-grafting reaction. The water contact angle of the treated PLA fabric is measured to be approximately 150 degrees, which is high enough to exhibit the Lotus effect as a result of the superhydrophobicity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrophobic and Hydrophilic Interactions
  • Lactic Acid / chemical synthesis*
  • Lactic Acid / chemistry
  • Particle Size
  • Polyesters
  • Polymers / chemical synthesis*
  • Polymers / chemistry
  • Silanes / chemistry*
  • Silicon Dioxide / chemistry*
  • Surface Properties
  • Temperature
  • Ultraviolet Rays

Substances

  • Polyesters
  • Polymers
  • Silanes
  • Lactic Acid
  • poly(lactide)
  • Silicon Dioxide
  • vinyltriethoxysilane