Measurement and computation of movement of bromide ions and carbofuran in ridged humic-sandy soil

Arch Environ Contam Toxicol. 2010 Jul;59(1):39-48. doi: 10.1007/s00244-009-9442-4. Epub 2009 Dec 30.

Abstract

Water flow and pesticide transport in the soil of fields with ridges and furrows may be more complex than in the soil of more level fields. Prior to crop emergence, the tracer bromide ion and the insecticide carbofuran were sprayed on the humic-sandy soil of a potato field with ridges and furrows. Rainfall was supplemented by sprinkler irrigation. The distribution of the substances in the soil profile of the ridges and furrows was measured on three dates in the potato growing season. Separate ridge and furrow systems were simulated by using the pesticide emission assessment at regional and local scales (PEARL) model for pesticide behavior in soil-plant systems. The substances travelled deeper in the furrow soil than in the ridge soil, because of runoff from the ridges to the furrows. At 19 days after application, the peak of the bromide distribution was measured to be in the 0.1-0.2 m layer of the ridges, while it was in the 0.3-0.5 m layer of the furrows. After 65 days, the peak of the carbofuran distribution in the ridge soil was still in the 0.1 m top layer, while the pesticide was rather evenly distributed in the top 0.6 m of the furrow soil. The wide ranges in concentration measured with depth showed that preferential water flow and substance transport occurred in the sandy soil. Part of the bromide ion distribution was measured to move faster in soil than the computed wave. The runoff of water and pesticide from the ridges to the furrows, and the thinner root zone in the furrows, are expected to increase the risk of leaching to groundwater in ridged fields, in comparison with more level fields.

MeSH terms

  • Bromides / analysis*
  • Bromides / chemistry
  • Carbofuran / analysis*
  • Carbofuran / chemistry
  • Humic Substances*
  • Kinetics
  • Models, Chemical
  • Pesticides / analysis*
  • Pesticides / chemistry
  • Silicon Dioxide / chemistry*
  • Soil Pollutants / analysis*
  • Soil Pollutants / chemistry
  • Water Movements

Substances

  • Bromides
  • Humic Substances
  • Pesticides
  • Soil Pollutants
  • Silicon Dioxide
  • Carbofuran