An endohedral titanium(III) in a clusterfullerene: putting a non-group-III metal nitride into the C(80)-I(h) fullerene cage

Chem Commun (Camb). 2009 Nov 14:(42):6391-3. doi: 10.1039/b911267g. Epub 2009 Sep 24.

Abstract

With the successful isolation of TiSc(2)N@C(80), the first Ti-containing nitride clusterfullerene (NCF), a non-group-III metal is stabilized in a NCF for the first time.