Oscillation in penetration distance in a train of chemical pulses propagating in an optically constrained narrowing channel

J Phys Chem A. 2009 Oct 1;113(39):10405-9. doi: 10.1021/jp903686k.

Abstract

A chemical wave train propagating in a narrowing excitable channel surrounded by a nonexcitable field is investigated by using a photosensitive Belousov-Zhabotinsky (BZ) reaction. The considered geometry is created as a dark triangle surrounded by an illuminated area where the reaction is suppressed by the light-induced generation of bromide ion. For a low illumination level, a pulse train terminates at a constant position. However, as the light intensity increases, the position at which subsequent pulses disappear changes periodically, so that the period-doubling of penetration depth occurs. Two-dimensional simulations based on a modified Oregonator model for the photosensitive BZ reaction reproduce the essential features of the experimental observation.