Synthesis and structure of an air-stable cationic organobismuth complex and its use as a highly efficient catalyst for the direct diastereoselective Mannich reaction in water

Renhua Qiu; Shuangfeng Yin; Xiaowen Zhang; Jun Xia; Xinhua Xu; Shenglian Luo

doi:10.1039/b908234d

Synthesis and structure of an air-stable cationic organobismuth complex and its use as a highly efficient catalyst for the direct diastereoselective Mannich reaction in water

Chem Commun (Camb). 2009 Aug 21:(31):4759-61. doi: 10.1039/b908234d. Epub 2009 Jul 6.

Authors

Renhua Qiu¹, Shuangfeng Yin, Xiaowen Zhang, Jun Xia, Xinhua Xu, Shenglian Luo

Affiliation

¹ College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.

PMID: 19641834
DOI: 10.1039/b908234d

Abstract

An air-stable cationic organobismuth complex was successfully synthesized and found to show high catalytic efficiency in the direct diastereoselective Mannich reaction in water.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Air
Bismuth / chemistry*
Catalysis
Cations / chemistry
Mannich Bases / chemistry
Molecular Structure
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Stereoisomerism
Water / chemistry*

Substances

Cations
Mannich Bases
Organometallic Compounds
Water
Bismuth