Room-temperature metal-hydride discharge source, with observations on NiH and FeH

J Phys Chem A. 2009 Nov 26;113(47):13159-66. doi: 10.1021/jp9033968.

Abstract

A metal sputtering source suitable for laboratory production of metal hydrides is described. Sputtering from pure nickel or iron in an Ar/H(2) discharge is analyzed at low resolution. High resolution laser excitation and dispersed fluorescence spectra of NiH have also been recorded. The source has been designed to operate with a ferromagnetic circuit for Zeeman spectroscopy. Signals from the source are strong enough to record dispersed fluorescence from NiH by Fourier transform interferometry in magnetic fields up to 1 T. We establish that FeH can also be formed in this source.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Argon / chemistry
  • Hydrogen / chemistry*
  • Iron / chemistry*
  • Nickel / chemistry*
  • Temperature*

Substances

  • Argon
  • Nickel
  • Hydrogen
  • Iron