Aging and yielding in a sheared AOT/iso-octane/water lyotropic lamellar phase

Eur Phys J E Soft Matter. 2009 May;29(1):51-60. doi: 10.1140/epje/i2009-10450-6. Epub 2009 May 3.

Abstract

We define a creep-flow-based measurement procedure to allow reliable and reproducible results on aging and yielding materials to be obtained. Investigation of the effects of different parameter such as the pre-shear time, the recovery time and the applied stress magnitude on the viscoelastic properties of a lyotropic liquid crystal phase is reported. Cryo-TEM observations indicate the formation of multiconnected bilayers at rest. Shearing the investigated material shows a propensity to acquire all the macroscopic properties of "soft jammed systems". These properties are then interpreted in terms of shear-induced structural rearrangement on the basis of cryofracture observation obtained at different times after the preshear imposed.

MeSH terms

  • Dioctyl Sulfosuccinic Acid / chemistry*
  • Octanes / chemistry*
  • Phase Transition*
  • Reproducibility of Results
  • Time Factors
  • Water / chemistry*

Substances

  • Octanes
  • Water
  • Dioctyl Sulfosuccinic Acid
  • octane