Softening of the radial breathing mode in metallic carbon nanotubes

Phys Rev Lett. 2009 Mar 27;102(12):126804. doi: 10.1103/PhysRevLett.102.126804. Epub 2009 Mar 25.

Abstract

The softening of the radial breathing mode (RBM) of metallic single walled carbon nanotubes (m-SWNTs) due to electron-phonon coupling has been studied by observing the Fermi level [see text] dependence of the RBM Raman peak. In situ Raman spectra were obtained from several individual m-SWNTs while varying [see text] electrochemically. The RBM frequency of an intrinsic m-SWNT is shown to be down-shifted relative to highly doped tubes by approximately 2 cm(1). The down-shift is greatest for small diameter and small chiral angle SWNTs. Most tubes show no change in RBM linewidth. A comparison is drawn between the RBM and the G band (A(LO) phonon) with respect to the [see text] dependence of their frequencies and linewidths.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Electrochemical Techniques
  • Lithium Compounds / chemistry
  • Metal Nanoparticles / chemistry*
  • Nanotubes, Carbon / chemistry*
  • Polyethylene Glycols / chemistry
  • Spectrum Analysis, Raman / methods

Substances

  • Lithium Compounds
  • Nanotubes, Carbon
  • Polyethylene Glycols