Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

Renhua Qiu; Xinhua Xu; Yinhui Li; Guoping Zhang; Lingling Shao; Delie An; Shuangfeng Yin

doi:10.1039/b821366f

Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

Chem Commun (Camb). 2009 Apr 7:(13):1679-81. doi: 10.1039/b821366f. Epub 2009 Feb 12.

Authors

Renhua Qiu¹, Xinhua Xu, Yinhui Li, Guoping Zhang, Lingling Shao, Delie An, Shuangfeng Yin

Affiliation

¹ College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.

PMID: 19294260
DOI: 10.1039/b821366f

Abstract

Air-stable Lewis acidic micro2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.