An Al(86)Mn(3)Be(11) alloy cast into copper mould was subjected to metallographic investigation. The as-cast microstructure consisted of a quasicrystalline icosahedral phase (i-phase), Be(4)AlMn phase and, occasionally, a hexagonal phase. Al-rich solid solution represented the dominant phase. The chemical compositions of phases were determined using AES. The composition of the Be(4)AlMn slightly deviated from the stoichiometric composition, whereas the composition of the i-phase was approximately Al(52)Mn(18)Be(30), containing an appreciable amount of Be. The average composition of the hexagonal phase was Al(66)Mn(21)Be(13). Deep etching and particle extraction provided a deep insight into the three-dimensional morphology of the i-phase and the hexagonal phase, whereas Be(4)AlMn was slightly attacked by the etchant. The i-phase was present predominantly in the form of dendrites and a rodlike eutectic phase. The hexagonal phase was primarily in the form of hexagonal platelets, whereas Be(4)AlMn was rather irregular in shape. The morphology of the i-phase can be explained by predominant growth in 3-fold directions and the lowest energy of the 5-fold planes, leading to the faceting and adopting a pentagonal dodecahedron shape. The brightnesses of phases in the backscattered electron images were rationalized by determining their backscattering coefficients. TEM investigation showed considerable phason strain in the i-phase, and the polycrystalline nature of the Be(4)AlMn phase.