Road traffic collisions while at work are the single largest cause of occupational fatality in the United Kingdom. Work-related road collisions do not comprise a homogenous group, but take many forms, encompassing the use of varying types of vehicle used for diverse purposes. A sample of over 2000 collision cases was considered, over 1000 in detail, from UK police forces, involving drivers/workers of all ages, and covering the years 1996-2004 inclusive. There were three key findings. (1) There were six main classes of collision-involved vehicles. These were company cars, vans/pickups, large goods vehicles (LGVs), buses (PCVs or 'passenger carrying vehicles'), taxis/minicabs, and emergency vehicles (police, fire/rescue and ambulance). (2) The drivers of company cars, vans/pickups, and large goods vehicles (LGVs) all appeared to have a high 'blameworthiness ratio' in their collision involvement. Company car drivers showed excess speed as a causal factor, whereas van drivers showed more observational failures, and LGV drivers showed more fatigue and vehicle defects as factors. (3) The drivers of buses (PCVs), taxis/minicabs, and emergency vehicles showed a low 'blameworthiness ratio' in their collision involvement. Their problems seemed to be primarily with the other drivers/parties with whom they share the road. While they made a variety of mistakes or errors, they were more likely to become the victim of another party's mistake or error.