Fabrication and photocatalytic property of Pt-intercalated layered perovskite niobates H(1-x)LaNb(2-x)Mo(x)O(7) (x=0-0.15)

Yunfang Huang; Jing Li; Yuelin Wei; Yibin Li; Jianmin Lin; Jihuai Wu

doi:10.1016/j.jhazmat.2008.11.040

Fabrication and photocatalytic property of Pt-intercalated layered perovskite niobates H(1-x)LaNb(2-x)Mo(x)O(7) (x=0-0.15)

J Hazard Mater. 2009 Jul 15;166(1):103-8. doi: 10.1016/j.jhazmat.2008.11.040. Epub 2008 Nov 21.

Authors

Yunfang Huang¹, Jing Li, Yuelin Wei, Yibin Li, Jianmin Lin, Jihuai Wu

Affiliation

¹ The Key Laboratory for College of Materials Science and Engineering, Huaqiao University of Fujian Higher Education, Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, China.

PMID: 19111974
DOI: 10.1016/j.jhazmat.2008.11.040

Abstract

H(1-x)LaNb(2-x)Mo(x)O(7) was prepared by solid-state reaction followed by an ion-exchange reaction. Pt was incorporated in the interlayer of H(1-x)LaNb(2-x)Mo(x)O(7) by the stepwise intercalation reaction. The H(1-x)LaNb(2-x)Mo(x)O(7) showed hydrogen production activity and the activities were greatly enhanced by Pt co-incorporating. The x value in H(1-x)LaNb(2-x)Mo(x)O(7) had an important effect on the photocatalytic activity of the catalyst. When the x=0.05, the H(1-x)LaNb(2-x)Mo(x)O(7)/Pt showed a photocatalytic activity of 80 cm(3)h(-1)g(-1) hydrogen evolution rate in 10 vol.% methanol solution under irradiation from a 100 W mercury lamp at 333K.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Calcium Compounds / chemical synthesis*
Calcium Compounds / chemistry
Catalysis
Hydrogen
Light
Oxides / chemical synthesis*
Oxides / chemistry
Photolysis*
Platinum / chemistry*
Titanium / chemistry

Substances

Calcium Compounds
Oxides
perovskite
Platinum
Hydrogen
Titanium