Intermodal four-wave mixing (FWM) in microstructured optical fibers (MOF) is studied theoretically and experimentally. The dependance of FWM frequency detuning on the geometrical parameters of the fiber, namely the pitch, the core width and the air-filling fraction is derived. We propose to use the results of this investigation to control the position of the Stokes and anti-Stokes waves directly from the fiber transverse structure drawing without the need for time-consuming simulations as in usual design procedures. Stokes sideband can then be freely tuned within the S-, L-, and C- bands with great potential for infrared applications.