Solid-state scrolls from hierarchical self-assembly of T-shaped rod-coil molecules

Angew Chem Int Ed Engl. 2009;48(9):1664-8. doi: 10.1002/anie.200804307.

Abstract

On a roll: Attachment of flexible coils to the middle of a rigid rod generates T-shaped rod-coil molecules that self-assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Liquid Crystals / chemistry*
  • Microscopy, Electron, Transmission
  • Molecular Conformation
  • Nanostructures / chemistry*
  • Surface-Active Agents / chemistry
  • Thermodynamics

Substances

  • Surface-Active Agents