A nanoporous chiral metal-organic framework material that exhibits reversible guest adsorption

Dalton Trans. 2008 Nov 28:(44):6103-5. doi: 10.1039/b816359f. Epub 2008 Oct 3.

Abstract

Assembly of the novel homochiral ligand L(S) (where L(S) is 1,4-benzylidene-bis(S,S)-4-yl-3,5-bis(1-hydroxyethyl)-1,2,4-triazole) and AgNO3 generates a robust, porous, chiral and cationic framework that exhibits reversible guest adsorption.

MeSH terms

  • Adsorption
  • Benzylidene Compounds / chemistry*
  • Ligands
  • Models, Chemical
  • Molecular Structure
  • Nanostructures / chemistry*
  • Porosity
  • Silver Nitrate / chemistry*
  • Stereoisomerism
  • Triazoles / chemistry*

Substances

  • 1,4-benzylidene-bis(S,S)-4-yl-3,5-bis(1-hydroxyethyl)-1,2,4-triazole
  • Benzylidene Compounds
  • Ligands
  • Triazoles
  • Silver Nitrate