Sequential titration of iron(II) and vanadium(IV) mixtures with cerium(IV) sulphate, with ferroins as indicators

K Sriramam; B S Sarma; N R Sastry; A R Prasad

doi:10.1016/0039-9140(82)80075-1

Sequential titration of iron(II) and vanadium(IV) mixtures with cerium(IV) sulphate, with ferroins as indicators

Talanta. 1982 Aug;29(8):687-8. doi: 10.1016/0039-9140(82)80075-1.

Authors

K Sriramam¹, B S Sarma, N R Sastry, A R Prasad

Affiliation

¹ Department of Chemistry, Nagarjuna University, Nagarjunanagar-522510 (A.P.), India.

PMID: 18963213
DOI: 10.1016/0039-9140(82)80075-1

Abstract

The titration of vanadium(IV) with cerium(IV) sulphate, with nitroferroin as indicator, is proposed. Unlike ferroin, the indicator does not need a catalyst in this system. By suitable choice of experimental conditions iron(II) can be titrated first to a ferroin end-point and then vanadium(IV) to a nitroferroin end-point.