Stepped strips from self-organization of oligo(p-phenylene) rods with lateral dendritic chains

J Am Chem Soc. 2008 Nov 5;130(44):14448-9. doi: 10.1021/ja807035j. Epub 2008 Oct 9.

Abstract

We have demonstrated that the rod segments with lateral dendritic chains self-assemble into unique stepped strips in which the rods are aligned parallel to the strip long axis. This unique organization of the rod segments arises from a balance between the energetic gain of a parallel arrangement of the rods and the resulting entropic penalty associated with stretching of the lateral flexible chains.