Abstract
(C(5)H(14)N(2))[(VO)(3)(AsO(4))(HAsO(4))(2)(OH)].3H(2)O behaves as a microporous organically templated compound, with reversible adsorption and desorption of N(2) at 77 K, and as an extremely efficient catalyst that catalyzes selective sulfoxide formation from organic sulfides, under mild conditions.
MeSH terms
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Adsorption
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Arsenates / chemistry*
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Catalysis
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Models, Molecular
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Molecular Structure
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Nitrogen / chemistry
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Organometallic Compounds / chemistry*
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Oxidation-Reduction
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Porosity
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Safrole / analogs & derivatives
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Safrole / chemical synthesis
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Safrole / chemistry
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Sulfides / chemistry
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Surface Properties
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Time Factors
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Vanadium Compounds / chemistry*
Substances
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Arsenates
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Organometallic Compounds
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Sulfides
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Vanadium Compounds
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Nitrogen
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arsenic acid
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Safrole
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sulfoxide