Abstract
C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzyl Compounds / chemistry*
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Cobalt / chemistry*
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Crystallography, X-Ray
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Cyclization
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Stereoisomerism
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Sulfides / chemistry*
Substances
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Benzyl Compounds
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Organometallic Compounds
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Sulfides
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Cobalt
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benzyl sulfide