Semiclassical origins of density functionals

Phys Rev Lett. 2008 Jun 27;100(25):256406. doi: 10.1103/PhysRevLett.100.256406. Epub 2008 Jun 27.

Abstract

The relation between semiclassical and density-functional approximations is clarified. Semiclassical approximations both explain and improve upon density-gradient expansions for finite systems. We derive highly accurate density and kinetic energy functionals of the potential in one dimension.