Variation of MCPA, metribuzine, methyltriazine-amine and glyphosate degradation, sorption, mineralization and leaching in different soil horizons

Environ Pollut. 2008 Dec;156(3):794-802. doi: 10.1016/j.envpol.2008.06.002. Epub 2008 Jul 21.

Abstract

Pesticide mineralization and sorption were determined in 75 soil samples from 15 individually drilled holes through the vadose zone along a 28km long transect of the Danish outwash plain. Mineralization of the phenoxyacetic acid herbicide MCPA was high both in topsoils and in most subsoils, while metribuzine and methyltriazine-amine was always low. Organic matter and soil pH was shown to be responsible for sorption of MCPA and metribuzine in the topsoils. The sorption of methyltriazine-amine in topsoil was positively correlated with clay and negatively correlated with the pH of the soil. Sorption of glyphosate was tested also high in the subsoils. One-dimensional MACRO modeling of the concentration of MCPA, metribuzine and methyltriazine-amine at 2m depth calculated that the average concentration of MCPA and methyltriazine-amine in the groundwater was below the administrative limit of 0.1mug/l in all tested profiles while metribuzine always exceeded the 0.1mug/l threshold value.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • 2-Methyl-4-chlorophenoxyacetic Acid / analysis*
  • Adsorption
  • Aluminum Silicates
  • Biodegradation, Environmental
  • Clay
  • Denmark
  • Environmental Monitoring / methods
  • Glycine / analogs & derivatives
  • Glycine / analysis
  • Glyphosate
  • Herbicides / analysis*
  • Hydrogen-Ion Concentration
  • Models, Statistical
  • Particle Size
  • Particulate Matter
  • Rivers
  • Soil / analysis*
  • Soil Pollutants / analysis*
  • Triazines / analysis
  • Water Pollutants, Chemical / analysis

Substances

  • Aluminum Silicates
  • Herbicides
  • Particulate Matter
  • Soil
  • Soil Pollutants
  • Triazines
  • Water Pollutants, Chemical
  • methyltriazine amine
  • 2-Methyl-4-chlorophenoxyacetic Acid
  • metribuzin
  • Clay
  • Glycine