Abstract
A method for the nucleophilic trifluoromethylation of N-benzoylhydrazones using Me3SiCF3/AcONa has been described. The CN bond of the hydrazones is activated by difluoroboron group, which is introduced by means of boron trifluoride and allylsilane.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene / chemistry*
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Crystallography, X-Ray
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Fluorine Compounds / chemistry*
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Hydrazones / chemical synthesis*
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Hydrazones / chemistry
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Methylation
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Models, Molecular
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Molecular Structure
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Silanes / chemistry
Substances
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Fluorine Compounds
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Hydrazones
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Silanes
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Benzene