Supramolecular engineering of a 2D Kagomé lattice: synthesis, structures, and magnetic properties

Yan-Feng Yue; Jue Liang; En-Qing Gao; Chen-Jie Fang; Zheng-Guang Yan; Chun-Hua Yan

doi:10.1021/ic800497n

Supramolecular engineering of a 2D Kagomé lattice: synthesis, structures, and magnetic properties

Inorg Chem. 2008 Jul 21;47(14):6115-7. doi: 10.1021/ic800497n. Epub 2008 Jun 14.

Authors

Yan-Feng Yue¹, Jue Liang, En-Qing Gao, Chen-Jie Fang, Zheng-Guang Yan, Chun-Hua Yan

Affiliation

¹ Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871, China.

PMID: 18553910
DOI: 10.1021/ic800497n

Abstract

Two 2D Mn (II) complexes, [Mn3(TzDC)2(phen)3] x 2 H2O (1; H3TzDC = 1,2,3-triazole-4,5-dicarboxylic acid, phen = 1,10-phenanthroline) and [Mn3(TzDC)2(bipy)3] x 4 H2O (2; bipy = 2,2'-bipyridine), were synthesized by hydrothermal reactions and characterized magnetically, and complex 1 was the first example of the chiral complex with a Kagomé lattice connectivity obtained through spontaneous resolution.