Abstract
A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox).
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Carbon Isotopes
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Carbon Monoxide / chemistry*
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Ferrous Compounds / chemistry*
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Hydrogenase / chemistry*
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Iron-Sulfur Proteins / chemistry*
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Ligands
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Molecular Conformation
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Oxidation-Reduction
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Stereoisomerism
Substances
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Carbon Isotopes
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Ferrous Compounds
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Iron-Sulfur Proteins
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Ligands
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Carbon Monoxide
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iron hydrogenase
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Hydrogenase