Conversion of anisotropically phase-segregated Pd/gamma-Fe2O3 nanoparticles into exchange-coupled fct-FePd/alpha-Fe nanocomposite magnets

J Am Chem Soc. 2008 Apr 2;130(13):4210-1. doi: 10.1021/ja077921v. Epub 2008 Mar 12.

Abstract

Exchange-coupled fct-FePd/alpha-Fe nanocomposite magnets were fabricated by converting anisotropically phase-segregated Pd/gamma-Fe2O3 nanoparticles via the interfacial atom diffusion. The magnetically hard fct-FePd phases formed by the interdiffusion between alpha-Fe and fcc-Pd phases nearly preserve their sizes at the nanometer scale because they are surrounded by the alpha-Fe matrix. The VSM measurements reveal that the exchange coupling between the soft and hard phases has been realized.