{Mu-N,N'-bis[2-(dimethylamino)ethyl]oxamidato(2-)-kappa(6)N,N',O':N'',N''',O}bis[(2,2'-bipyridine-kappa2N,N')copper(II)] bis(perchlorate)

Wei Sun; Yan-Tuan Li; Zhi-Yong Wu; Shu-Fang Zhang; Zhi-Wei Yin

doi:10.1107/S0108270107067558

{Mu-N,N'-bis[2-(dimethylamino)ethyl]oxamidato(2-)-kappa(6)N,N',O':N'',N''',O}bis[(2,2'-bipyridine-kappa2N,N')copper(II)] bis(perchlorate)

Acta Crystallogr C. 2008 Mar;64(Pt 3):m108-10. doi: 10.1107/S0108270107067558. Epub 2008 Feb 9.

Authors

Wei Sun¹, Yan-Tuan Li, Zhi-Yong Wu, Shu-Fang Zhang, Zhi-Wei Yin

Affiliation

¹ Marine Drug and Food Institute, Ocean University of China, 266003 Qingdao, People's Republic of China.

PMID: 18322318
DOI: 10.1107/S0108270107067558

Abstract

In the crystal structure of the title complex, [Cu(2)(C(10)H(20)N(4)O(2))(C(10)H(8)N(2))(2)](ClO(4))(2), the deprotonated dmaeoxd(2-) ligand {H(2)dmaeoxd is N,N'-bis[2-(dimethylamino)ethyl]oxamide} occupies an inversion centre at the mid-point of the central C-C bond and is thus in a trans conformation. The two Cu(II) atoms are located in slightly distorted square-based pyramidal environments. The binuclear units interact with each other via pi-pi interactions to form a one-dimensional chain extending in the c direction.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Models, Molecular
Molecular Structure
Organometallic Compounds / chemistry*

Substances

(mu-N,N'-bis(2-(dimethylamino)ethyl)oxamidato(2-)-kappa(6)N,N',O'-N'',N''',O)bis((2,2'-bipyridine-kappa2N,N')copper(III))
Organometallic Compounds