Spectroscopic studies of zinc(II)tetraphenylporphyrin molecular complex with 1,4-dioxane

N Sh Lebedeva; A I Karelin; N A Pavlycheva; W Zielenkiewicz; R Swierzewski

doi:10.1016/j.saa.2008.01.007

Spectroscopic studies of zinc(II)tetraphenylporphyrin molecular complex with 1,4-dioxane

Spectrochim Acta A Mol Biomol Spectrosc. 2008 Sep;70(4):939-42. doi: 10.1016/j.saa.2008.01.007. Epub 2008 Jan 11.

Authors

N Sh Lebedeva¹, A I Karelin, N A Pavlycheva, W Zielenkiewicz, R Swierzewski

Affiliation

¹ Institute of Solution Chemistry of Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo 153045, Russian Federation. nsl@isc-ras.ru

PMID: 18280785
DOI: 10.1016/j.saa.2008.01.007

Abstract

The molecular complex of zinc(II)tetraphenylporphyrin with 1,4-dioxane has been obtained. The IR spectra of the [Zn(TPhP)(1,4-dioxane)2] stabile molecular complex between 4000 and 50cm(-1) have been studied. An interpretation is given on the base the "chair" conformation of 1,4-dioxane molecule.

MeSH terms

Dioxanes / chemistry*
Metalloporphyrins / chemistry*
Molecular Structure
Spectrophotometry, Infrared

Substances

Dioxanes
Metalloporphyrins
zinc tetraphenylporphyrin
1,4-dioxane