A templating approach for monodisperse self-assembled organic nanostructures

J Am Chem Soc. 2008 Mar 5;130(9):2742-3. doi: 10.1021/ja710749q. Epub 2008 Feb 12.

Abstract

The precise structural control is known for self-assembly into closed spherical structures (e.g., micelles), but similar control of open structures is much more challenging. Inspired by natural tobacco mosaic virus, we present the use of a rigid-rod template to control the size of a one-dimensional self-assembly. We believe that this strategy is novel for organic self-assembly and should provide a general approach to controlling size and dimension.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Aluminum Silicates / chemistry
  • Hydrophobic and Hydrophilic Interactions
  • Microscopy, Atomic Force
  • Microscopy, Electron, Transmission
  • Models, Molecular
  • Molecular Structure
  • Nanostructures / chemistry*
  • Particle Size
  • Peptides / chemical synthesis*
  • Peptides / chemistry
  • Polyethylene Glycols / chemistry
  • Polymers / chemical synthesis*
  • Polymers / chemistry
  • Protein Conformation
  • Protein Structure, Secondary
  • Surface Properties

Substances

  • Aluminum Silicates
  • Peptides
  • Polymers
  • poly(phenylene ethynylene)
  • Polyethylene Glycols
  • mica