Rh(II)-catalyzed Sommelet-Hauser rearrangement

Org Lett. 2008 Mar 6;10(5):693-6. doi: 10.1021/ol703058p. Epub 2008 Feb 1.

Abstract

Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.