Hydrothermal synthesis and structural characterization of the first mixed molybdenum-tungsten capped-keggin polyoxometal complex: {[Co(dien)]4[(AsVO4)MoV8WVI4O33(micro2-OH)3]}.2H2O

Dalton Trans. 2008 Jan 14:(2):195-7. doi: 10.1039/b711604g. Epub 2007 Oct 19.

Authors

Hai-Hui Yu¹, Xiao-Bing Cui, Ji-Wen Cui, Li Kong, Wei-Jie Duan, Ji-Qing Xu, Tie-Gang Wang

Affiliation

¹ College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, PR China.

PMID: 18097484
DOI: 10.1039/b711604g

Abstract

The first polyoxometal complex possessing affirmatory mixed molybdenum-tungsten capped Keggin-type structure has been hydrothermally synthesized.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Arsenic / chemistry*
Crystallography, X-Ray
Indicators and Reagents
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Conformation
Molybdenum / chemistry*
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Oxidation-Reduction
Tungsten / chemistry*

Substances

Indicators and Reagents
Organometallic Compounds
Molybdenum
Arsenic
Tungsten