Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages

Kazunari Ohgaki; Kentaro Nakatsuji; Kei Takeya; Atsushi Tani; Takeshi Sugahara

doi:10.1039/b715284a

Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages

Phys Chem Chem Phys. 2008 Jan 7;10(1):80-2. doi: 10.1039/b715284a. Epub 2007 Nov 20.

Authors

Kazunari Ohgaki¹, Kentaro Nakatsuji, Kei Takeya, Atsushi Tani, Takeshi Sugahara

Affiliation

¹ Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. ohgaki@cheng.es.osaka-u.ac.jp

PMID: 18075685
DOI: 10.1039/b715284a

Abstract

Electron spin resonance measurement of gamma-ray-irradiated propane hydrates shows that the normal propyl radical withdraws hydrogen from the adjacent propane molecule through the hexagonal planes of the hydrate cage without water molecule bridging.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Electron Spin Resonance Spectroscopy
Free Radicals / chemistry
Free Radicals / radiation effects
Gamma Rays
Hydrogen / chemistry*
Hydrogen / radiation effects
Propane / chemistry*
Propane / radiation effects
Temperature
Time Factors
Water / chemistry

Substances

Free Radicals
Water
Hydrogen
Propane