A new coordination mode of 6-methylnicotinic acid in trans-tetraaquabis(6-methylpyridine-3-carboxylato-kappaO)cobalt(II) tetrahydrate

Acta Crystallogr C. 2007 Dec;63(Pt 12):m615-7. doi: 10.1107/S0108270107056570. Epub 2007 Nov 30.

Abstract

The title compound, [Co(C7H6NO2)2(H2O)4] x 4 H2O, contains a Co(II) ion lying on a crystallographic inversion centre. The Co(II) ion is octahedrally coordinated by two 6-methylpyridine-3-carboxylate ligands in axial positions [Co-O = 2.0621 (9) A] and by four water molecules in the equatorial plane [Co-O = 2.1169 (9) and 2.1223 (11) A]. There are also four uncoordinated water molecules. The 6-methylpyridine-3-carboxylate ligands are bound to the Co(II) ion in a monodentate manner through a carboxylate O atom. There is one strong intramolecular O-H...O hydrogen bond, and six strong intermolecular hydrogen bonds of type O-H...O and one of type O-H...N in the packing, resulting in a complex three-dimensional supramolecular structure.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cobalt / chemistry*
  • Crystallography, X-Ray
  • Ligands
  • Molecular Structure
  • Nicotinic Acids / chemistry*
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Pyridines / chemistry*

Substances

  • Ligands
  • Nicotinic Acids
  • Organometallic Compounds
  • Pyridines
  • tetraaquabis(6-methylpyridine-3-carboxylato-kappaO)cobalt(II)
  • Cobalt
  • methyl nicotinate