Abstract
We describe the synthesis and structures of the first tantalum-containing nitride-chlorides, Ba(3)Ta(3)N(6)Cl and Ba(15)Ta(15)N(33)Cl(4), and the structurally related Ba(3)Si(3)N(5)OCl, and their relationship with a theoretical silaceous framework.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Barium / chemistry*
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Chlorides / chemistry*
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Crystallography, X-Ray
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Models, Molecular
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Nitrogen Compounds / chemical synthesis
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Nitrogen Compounds / chemistry*
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Particle Size
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Silicates / chemistry*
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Surface Properties
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Tantalum / chemistry*
Substances
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Chlorides
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Nitrogen Compounds
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Silicates
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Barium
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Tantalum