L-proline catalyzed Michael additions of thiophenols to alpha,beta-unsaturated compounds, particularly alpha-enones, in the ionic liquid [bmim]PF6

Molecules. 2006 Mar 17;11(2):197-205. doi: 10.3390/11020197.

Abstract

L-proline catalyzed additions of 13 different thiols to 11 different alpha-enone Michael acceptors in [bmim] PF(6 )are reported. Reasonable to high yields of the reaction products were isolated in most cases.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Cycloparaffins / chemical synthesis
  • Cycloparaffins / chemistry*
  • Ionic Liquids*
  • Kinetics
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Molecular Structure
  • Organic Chemicals / chemistry*
  • Phenols / chemistry*
  • Proline / chemistry*
  • Solvents
  • Sulfhydryl Compounds / chemistry*

Substances

  • Cycloparaffins
  • Ionic Liquids
  • Organic Chemicals
  • Phenols
  • Solvents
  • Sulfhydryl Compounds
  • thiophenol
  • Proline