Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Houng Sik Yoo; Jae Il Kim; Namgeun Yang; Eui Kwan Koh; Je-Geun Park; Chang Seop Hong

doi:10.1021/ic7014995

Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Inorg Chem. 2007 Oct 29;46(22):9054-6. doi: 10.1021/ic7014995. Epub 2007 Sep 27.

Authors

Houng Sik Yoo¹, Jae Il Kim, Namgeun Yang, Eui Kwan Koh, Je-Geun Park, Chang Seop Hong

Affiliation

¹ Department of Chemistry, Korea University, Seoul, Korea.

PMID: 17900108
DOI: 10.1021/ic7014995

Abstract

A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2].MeCN (1.MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Azides / chemistry*
Copper / chemistry*
Iron / chemistry*
Magnetics
Models, Molecular

Substances

Azides
Copper
Iron