Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned ironIII cyanide precursor

Inorg Chem. 2007 Oct 15;46(21):8481-3. doi: 10.1021/ic701361a. Epub 2007 Sep 13.

Abstract

A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN)(3)]- (1), and a zigzag chain, [Fe(pzcq)(CN)(3)][Mn(salen)].4H(2)O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry, Inorganic / methods*
  • Crystallography, X-Ray / methods
  • Cyanides / analysis
  • Ferric Compounds / chemistry
  • Ferricyanides / chemistry*
  • Iron / chemistry*
  • Ligands
  • Magnetics
  • Molecular Conformation
  • Molecular Structure
  • Oscillometry
  • Temperature

Substances

  • Cyanides
  • Ferric Compounds
  • Ferricyanides
  • Ligands
  • Iron
  • ferric ferricyanide