Oxygen isotope effect in high-temperature oxide superconductors

Science. 1987 Dec 11;238(4833):1558-60. doi: 10.1126/science.238.4833.1558.

Abstract

The effect of oxygen isotope substitution on the superconducting transition temperature, T(c), has been measured for BaBi(0.25)Pb(0.75)O(3) (T(c), approximately 11 K) and Lal(1.85) Ca(0.15)CuO(4) (T(c) approximately 20 K), and is compared to the shifts observed for La(1.85)Sr(0.15)CuO(4) (T(c) approximately 37 K) and YBa(2)Cu(3)O(7) (T(c) approximately 92 K). For all four materials, the transition temperature is shifted to lower temperature upon substitution of oxygen-18 for oxygen-16. The observed shifts demonstrate that phonons are involved in the electron-pairing mechanism in these oxide superconductors.